Ep slicone underfill
Characteristics
- Cross-linked silicone particles dispersed in epoxy resin relieves stress from thermal and also mechanical shocks.
- Hard to crack
- It absorbs flux residue which allows for better filling underneath the device.
- Synergy between silicone and filler makes the CTE drop lower. With the same filler content(%), Ep silicone has lower CTE level than ordinary epoxy.
- Lower CTE works to relieve stress on a PCB in the process of curing.
Ep silicone sea island structure
SEM pix Ep silicone
Sunstar's original polymer technology innovated epoxy formulation for electronics industry. This sea-island structure makes the epoxy resin flexible and hard to crack. It absorbs stress from thermal and mechanical shocks. All our UF materials are based on this unique structure.
It absorbs flux residue left on a PC
The underfill absorbs flux residue inside and thereby prevents
voids from affecting the reliability of underfilled CSP.
Experiment
Apply flux on to FR-4 ⇒ heat 3 min. at 220 degrees ⇒ apply UF from above and cures at 150 degrees 30 minutes ⇒ cross-section examination
THB test after UF absorbing flux residue
Test steps
- Apply flux to IR {50µm(t)}and oven-dry at 230c for 2 min.&
- Apply underfill to the IR{200µm(t)}and cured at 150c for 30 min.
- Subject the IR to 85c85% environment, and after 1 hour, obtain an initial insulation value by applying measurement voltage of 100V. Subject the IR to the impressed voltage of 10V for 2000 hours.}
(100V when measuring insulation resistance value.)
Physical property
| RD-11262 | RD-0353B | RD-0324GF40 | RD-0324G1 | Others | ||
|---|---|---|---|---|---|---|
| Cure Condition | 125c × 20min | 150c × 30min | 150c × 30min | 150c × 30min | ||
| Application | car | Car/FC | FC | FC | ||
| Key Word | Low CTE | Low CTE | Low CTE | Low CTE | ||
| Appearance | Black | Black | Black | Black | ||
| Viscosity (m Pa ·s) |
51400 | 15000 | 2500 | 8600 | BH 20c | |
| Filler (%) | 63 | 70 | 40 | 55 | ||
| Tg () | 127 | 139 | 134 | 127 | TMA | |
| CTE | a1 | 25 | 20 | 42 | 32 | TMA |
| α2 | 45 | 45 | 71 | 67 | ||
| Flexural modulus ( N/ mm 2 ) |
6500 | 9000 | 3200 | 6200 | JIS K 6911 | |
| Flexural strength ( N/ mm 2 ) |
120 | 120 | 120 | 120 | JIS K 6911 | |
| Adhesion | 8.5 | 8 | 7 | 6 | JIS K6850 Al- Al | |
| 1090 | 1091E | RD-0377F | RD-11262A | Others | ||
|---|---|---|---|---|---|---|
| Cure Condition | 150c × 10min | 150c × 30min | 150c × 10min | 125c × 20min | ||
| Application | mobile | mobile/car | mobile/car | mobile/car | ||
| Key Word | flexible | for WLCSP | for WLCSP | for WLCSP | ||
| Appearance | yellow | Black | Black | Black | ||
| Viscosity (m Pa ·s) |
5000 | 1500 | 7000 | 11200 | BH type 20c | |
| Filler (%) | - | 30 | 60 | 55 | ||
| Tg () | 122 | 134 | 148 | 120 | TMA | |
| CTE | a1 | 88 | 49 | 24 | 38 | TMA |
| α2 | 205 | 98 | 84 | 54 | ||
| Flexural modulus ( N/ mm 2 ) |
3500 | 3500 | 7000 | 4400 | JIS K 6911 | |
| Flexural strength ( N/ mm 2 ) |
110 | 125 | 130 | 110 | JIS K 6911 | |
| Adhesion | 4 | 4 | 8 | 9.3 | JIS K6850 Al- Al | |